上游原料
1-Methoxy-1-methylethyl methyl ether; 2,2-Dimethoxypropane3-Bromo-1-propene; 3-Bromopropene；allyl bromidecyclohexanamine; cyclohexyl amine; cyclohexylaminedimethyl malonate；Methyl malonate;Propanedioic acid dimethyl estertert-butyl(3-iodopropoxy)dimethylsilane; tert-butyl(dimethyl)silyl 3-iodopropyl etherdimethyl 2-(3-[[tert-butyl(dimethyl)silyl]oxy]propyl)malonatedimethyl 2-allyl-2-(3-[[tert-butyl(dimethyl)silyl]oxy]propyl)malonate2-allyl-2-(3-[[tert-butyl(dimethyl)silyl]oxy]propyl)-1,3-propanediol3-(5-allyl-2,2-dimethyl-1,3-dioxan-5-yl)propyl tert-butyl(dimethyl)silyl ether; [3-(5-allyl-2,2-dimethyl-1,3-dioxan-5-yl)propoxy](tert-butyl)dimethylsilane2-[5-(3-[[tert-butyl(dimethyl)silyl]oxy]propyl)-2,2-dimethyl-1,3-dioxan-5-yl]acetaldehydeN-[(E)-2-[5-(3-[[tert-butyl(dimethyl)silyl]oxy]propyl)-2,2-dimethyl-1,3-dioxan-5-yl]ethylidene]-N-cyclohexylamine; N-[(E)-2-[5-(3-[[tert-butyl(dimethyl)silyl]oxy]propyl)-2,2-dimethyl-1,3-dioxan-5-yl]ethylidene]cyclohexanamine(E)-8-decenal(2Z,10E)-2-[5-(3-[[tert-butyl(dimethyl)silyl]oxy]propyl)-2,2-dimethyl-1,3-dioxan-5-yl]-2,10-dodecadienaltert-butyl[3-(5-[(2E,9E)-1-[(E)-2-(4-methoxyphenyl)ethylidene]-2,9-undecadienyl]-2,2-dimethyl-1,3-dioxan-5-yl)propoxy]dimethylsilane; tert-butyl(dimethyl)silyl 3-(5-[(2E,9E)-1-[(E)-2-(4-methoxyphenyl)ethylidene]-2,9-undecadienyl]-2,2-dimethyl-1,3-dioxan-5-yl)propyl ether3-(5-[(2E,9E)-1-[(E)-2-(4-methoxyphenyl)ethylidene]-2,9-undecadienyl]-2,2-dimethyl-1,3-dioxan-5-yl)-1-propanol3-(5-[(2E,9E)-1-[(E)-2-(4-methoxyphenyl)ethylidene]-2,9-undecadienyl]-2,2-dimethyl-1,3-dioxan-5-yl)propanal(E)-4-iodo-3-butenyl triisopropylsilyl ether; [[(E)-4-iodo-3-butenyl]oxy](triisopropyl)silane(E)-1-(5-[(2E,9E)-1-[(E)-2-(4-methoxyphenyl)ethylidene]-2,9-undecadienyl]-2,2-dimethyl-1,3-dioxan-5-yl)-7-[(triisopropylsilyl)oxy]-4-hepten-3-one(E)-1-(5-[(2E,9E)-1-[(E)-2-(4-methoxyphenyl)ethylidene]-2,9-undecadienyl]-2,2-dimethyl-1,3-dioxan-5-yl)-7-[(triisopropylsilyl)oxy]-4-hepten-3-one [2-[(E)-3-pentenyl]-1,3-dithian-2-yl]lithium indoline (9S,12S,13S,15R,18R)-18-[[tert-butyl(dimethyl)silyl]oxy]-9-[2-(2,3-dihydro-1H-indol-1-yl)-2-oxoethyl]-15-[(E)-4-hexenoyl]-12-[(E)-6-octenyl]-5,16,17-trioxapentacyclo[7.7.2.0(1,10).0(2,13).0(3,7)]octadeca-3(7),10-diene-4,6-dione(9S,12S,13S,15R,18S)-9-[2-(2,3-dihydro-1H-indol-1-yl)-2-oxoethyl]-15-[(E)-4-hexenoyl]-18-hydroxy-12-[(E)-6-octenyl]-5,16,17-trioxapentacyclo[7.7.2.0(1,10).0(2,13).0(3,7)]octadeca-3(7),10-diene-4,6-dione(9S,12S,13S,15R)-9-[2-(2,3-dihydro-1H-indol-1-yl)-2-oxoethyl]-15-[(E)-4-hexenoyl]-12-[(E)-6-octenyl]-5,16,17-trioxapentacyclo[7.7.2.0(1,10).0(2,13).0(3,7)]octadeca-3(7),10-diene-4,6,18-trione(9S,12S,13S,15R)-15-[(E)-4-hexenoyl]-9-[2-(1H-indol-1-yl)-2-oxoethyl]-12-[(E)-6-octenyl]-5,16,17-trioxapentacyclo[7.7.2.0(1,10).0(2,13).0(3,7)]octadeca-3(7),10-diene-4,6,18-trione(9S,12S,13S,15R)-15-[(E)-4-hexenoyl]-9-[2-(1H-indol-1-yl)-2-oxoethyl]-12-[(E)-6-octenyl]-5,16,17-trioxapentacyclo[7.7.2.0(1,10).0(2,13).0(3,7)]octadeca-3(7),10-diene-4,6,18-trione2-[(14S,15S)-11-hydroxy-15-[(2R,6E)-2-hydroxy-3-oxo-6-octenyl]-14-[(E)-6-octenyl]-3,5,9-trioxo-4,10-dioxatetracyclo[9.4.0.0(2,6).0(8,12)]pentadeca-2(6),12-dien-8-yl]acetic acid3-Bromo-1-propene; 3-Bromopropene；allyl bromidecyclohexanamine; cyclohexyl amine; cyclohexylaminedimethyl malonate；Methyl malonate;Propanedioic acid dimethyl estertert-butyl(3-iodopropoxy)dimethylsilane; tert-butyl(dimethyl)silyl 3-iodopropyl etherdimethyl 2-(3-[[tert-butyl(dimethyl)silyl]oxy]propyl)malonatedimethyl 2-allyl-2-(3-[[tert-butyl(dimethyl)silyl]oxy]propyl)malonate2-allyl-2-(3-[[tert-butyl(dimethyl)silyl]oxy]propyl)-1,3-propanediol3-(5-allyl-2,2-dimethyl-1,3-dioxan-5-yl)propyl tert-butyl(dimethyl)silyl ether; [3-(5-allyl-2,2-dimethyl-1,3-dioxan-5-yl)propoxy](tert-butyl)dimethylsilane2-[5-(3-[[tert-butyl(dimethyl)silyl]oxy]propyl)-2,2-dimethyl-1,3-dioxan-5-yl]acetaldehydeN-[(E)-2-[5-(3-[[tert-butyl(dimethyl)silyl]oxy]propyl)-2,2-dimethyl-1,3-dioxan-5-yl]ethylidene]-N-cyclohexylamine; N-[(E)-2-[5-(3-[[tert-butyl(dimethyl)silyl]oxy]propyl)-2,2-dimethyl-1,3-dioxan-5-yl]ethylidene]cyclohexanamine(E)-8-decenal(2Z,10E)-2-[5-(3-[[tert-butyl(dimethyl)silyl]oxy]propyl)-2,2-dimethyl-1,3-dioxan-5-yl]-2,10-dodecadienaltert-butyl[3-(5-[(2E,9E)-1-[(E)-2-(4-methoxyphenyl)ethylidene]-2,9-undecadienyl]-2,2-dimethyl-1,3-dioxan-5-yl)propoxy]dimethylsilane; tert-butyl(dimethyl)silyl 3-(5-[(2E,9E)-1-[(E)-2-(4-methoxyphenyl)ethylidene]-2,9-undecadienyl]-2,2-dimethyl-1,3-dioxan-5-yl)propyl ether3-(5-[(2E,9E)-1-[(E)-2-(4-methoxyphenyl)ethylidene]-2,9-undecadienyl]-2,2-dimethyl-1,3-dioxan-5-yl)-1-propanol3-(5-[(2E,9E)-1-[(E)-2-(4-methoxyphenyl)ethylidene]-2,9-undecadienyl]-2,2-dimethyl-1,3-dioxan-5-yl)propanal(2S)oxiranylmethanolethynyl(trimethyl)silane；trimethylsilyl acetylene3-(5-[(2E,9E)-1-[(E)-2-(4-methoxyphenyl)ethylidene]-2,9-undecadienyl]-2,2-dimethyl-1,3-dioxan-5-yl)propanal [2-[(E)-3-pentenyl]-1,3-dithian-2-yl]lithium tert-butyl(dimethyl)silyl (1R)-1-([[tert-butyl(dimethyl)silyl]oxy]methyl)-4-(trimethylsilyl)-3-butynyl ether; (5R)-2,2,3,3,8,8,9,9-octamethyl-5-[3-(trimethylsilyl)-2-propynyl]-4,7-dioxa-3,8-disiladecanetert-butyl(dimethyl)silyl (2R,4E)-2-[[tert-butyl(dimethyl)silyl]oxy]-5-iodo-4-pentenyl ether; (5R)-5-[(E)-3-iodo-2-propenyl]-2,2,3,3,8,8,9,9-octamethyl-4,7-dioxa-3,8-disiladecane(E,7R)-7,8-bis[[tert-butyl(dimethyl)silyl]oxy]-1-(5-[(2E,9E)-1-[(E)-2-(4-methoxyphenyl)ethylidene]-2,9-undecadienyl]-2,2-dimethyl-1,3-dioxan-5-yl)-4-octen-3-one Oxalic acid (8S,14R,15R)-15-((2S,6E)-2-[[tert-butyl(dimethyl)silyl]oxy]-3-oxo-6-octenyl)-11-hydroxy-8-(hydroxymethyl)-14-[(E)-6-octenyl]-4,10-dioxatetracyclo[9.4.0.0(2,6).0(8,12)]pentadeca-2(6),12-diene-3,5-dione(8R,14R,15R)-15-((2S,6E)-2-[[tert-butyl(dimethyl)silyl]oxy]-3-oxo-6-octenyl)-11-hydroxy-14-[(E)-6-octenyl]-8-[[(triethylsilyl)oxy]methyl]-4,10-dioxatetracyclo[9.4.0.0(2,6).0(8,12)]pentadeca-2(6),12-diene-3,5-dioneindoline (9S,12S,13S,15R,18R)-18-[[tert-butyl(dimethyl)silyl]oxy]-9-[2-(2,3-dihydro-1H-indol-1-yl)-2-oxoethyl]-15-[(E)-4-hexenoyl]-12-[(E)-6-octenyl]-5,16,17-trioxapentacyclo[7.7.2.0(1,10).0(2,13).0(3,7)]octadeca-3(7),10-diene-4,6-dione(9S,12S,13S,15R,18S)-9-[2-(2,3-dihydro-1H-indol-1-yl)-2-oxoethyl]-15-[(E)-4-hexenoyl]-18-hydroxy-12-[(E)-6-octenyl]-5,16,17-trioxapentacyclo[7.7.2.0(1,10).0(2,13).0(3,7)]octadeca-3(7),10-diene-4,6-dione(9S,12S,13S,15R,18S)-9-[2-(2,3-dihydro-1H-indol-1-yl)-2-oxoethyl]-15-[(E)-4-hexenoyl]-18-hydroxy-12-[(E)-6-octenyl]-5,16,17-trioxapentacyclo[7.7.2.0(1,10).0(2,13).0(3,7)]octadeca-3(7),10-diene-4,6-dione(9S,12S,13S,15R)-9-[2-(2,3-dihydro-1H-indol-1-yl)-2-oxoethyl]-15-[(E)-4-hexenoyl]-12-[(E)-6-octenyl]-5,16,17-trioxapentacyclo[7.7.2.0(1,10).0(2,13).0(3,7)]octadeca-3(7),10-diene-4,6,18-trione(9S,12S,13S,15R)-15-[(E)-4-hexenoyl]-9-[2-(1H-indol-1-yl)-2-oxoethyl]-12-[(E)-6-octenyl]-5,16,17-trioxapentacyclo[7.7.2.0(1,10).0(2,13).0(3,7)]octadeca-3(7),10-diene-4,6,18-trione2-[(14S,15S)-11-hydroxy-15-[(2R,6E)-2-hydroxy-3-oxo-6-octenyl]-14-[(E)-6-octenyl]-3,5,9-trioxo-4,10-dioxatetracyclo[9.4.0.0(2,6).0(8,12)]pentadeca-2(6),12-dien-8-yl]acetic acidmethyl 4-(propylsulfanyl)-2-butynoatemethyl 4-(propylsulfanyl)-2,3-butadienoate(1E,8E)-1,8-decadienylcoppermethyl (4E,11E)-3-[(E)-(propylsulfanyl)methylidene]-4,11-tridecadienoatedimethyl 2-[(2E,9E)-1-[(Z)-(propylsulfanyl)methylidene]-2,9-undecadienyl]malonate(4S)-3-acryloyl-4-benzyl-1,3-oxazolidin-2-onedimethyl 2-[3-[(4S)-4-benzyl-2-oxo-1,3-oxazolidin-3-yl]-3-oxopropyl]-2-[(2E,9E)-1-[(E)-(propylsulfanyl)methylidene]-2,9-undecadienyl]malonate(E)-4-[(4S,5S)-5-butyl-2,2-dimethyl-1,3-dioxolan-4-yl]-2-butenaldimethyl 2-[(2S,4E)-2-[[(4S)-4-benzyl-2-oxo-1,3-oxazolidin-3-yl]carbonyl]-6-[(4S,5S)-5-butyl-2,2-dimethyl-1,3-dioxolan-4-yl]-3-oxo-4-hexenyl]-2-[(2E,9E)-1-[(E)-(propylsulfanyl)methylidene]-2,9-undecadienyl]malonatedimethyl (4S,6R,7R,8R,10R)-4-[[(4S)-4-benzyl-2-oxo-1,3-oxazolidin-3-yl]carbonyl]-7-[[(4S,5S)-5-butyl-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-8-[(E)-6-octenyl]-5-oxo-10-(propylsulfanyl)bicyclo[4.3.1]dec-1(9)-ene-2,2-dicarboxylateallyl 2-sulfanylacetatedimethyl (4S,6R,7R,8R,10R)-4-([[2-(allyloxy)-2-oxoethyl]sulfanyl]carbonyl)-7-[[(4S,5S)-5-butyl-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-8-[(E)-6-octenyl]-5-oxo-10-(propylsulfanyl)bicyclo[4.3.1]dec-1(9)-ene-2,2-dicarboxylate3-allyl 8,8-dimethyl (1R,2R,3S,11R,12R,13R)-12-[[(4S,5S)-5-butyl-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-2-hydroxy-11-[(E)-6-octenyl]-5-oxo-13-(propylsulfanyl)-4-thiatricyclo[7.3.1.0(2,6)]tridec-9-ene-3,8,8-tricarboxylatedimethyl (1R,11R,12R,13R)-12-[[(4S,5S)-5-butyl-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-11-[(E)-6-octenyl]-5-oxo-13-(propylsulfanyl)-4-thiatricyclo[7.3.1.0(2,6)]trideca-2(6),9-diene-8,8-dicarboxylatedimethyl (1R,11R,12R,13R)-12-[[(4S,5S)-5-butyl-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-11-[(E)-6-octenyl]-3,5-dioxo-13-(propylsulfanyl)-4-thiatricyclo[7.3.1.0(2,6)]trideca-2(6),9-diene-8,8-dicarboxylatedimethyl (1R,11R,12R,13R)-12-[[(4S,5S)-5-butyl-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-11-[(E)-6-octenyl]-3,5-dioxo-13-(propylsulfanyl)-4-thiatricyclo[7.3.1.0(2,6)]trideca-2(6),9-diene-8,8-dicarboxylate(1R,8R,11R,12R,13R)-12-[[(4S,5S)-5-butyl-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-8-(methoxycarbonyl)-11-[(E)-6-octenyl]-3,5-dioxo-13-(propylsulfanyl)-4-oxatricyclo[7.3.1.0(2,6)]trideca-2(6),9-diene-8-carboxylic acidmethyl (1R,8S,11R,12R,13R)-8-[2-(tert-butoxy)-2-oxoethyl]-12-[[(4S,5S)-5-butyl-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-11-[(E)-6-octenyl]-3,5-dioxo-13-(propylsulfanyl)-4-oxatricyclo[7.3.1.0(2,6)]trideca-2(6),9-diene-8-carboxylatemethyl (1R,8S,11R,12R)-8-[2-(tert-butoxy)-2-oxoethyl]-12-[[(4S,5S)-5-butyl-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-11-[(E)-6-octenyl]-3,5,13-trioxo-4-oxatricyclo[7.3.1.0(2,6)]trideca-2(6),9-diene-8-carboxylatetert-butyl 2-[(2R,12R,13S,14R,15S)-14-butyl-15-(hydroxymethyl)-12-[(E)-6-octenyl]-4,6,18-trioxo-5,16,17-trioxapentacyclo[7.7.2.0(1,10).0(2,13).0(3,7)]octadeca-3(7),10-dien-9-yl]acetate
