英文名 | Benzyl alcohol |
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类型 | 芳香族化合物 |
CAS号 | 100-51-6 |
物理性质 | M 107.2, f -15.3℃, b 205.5℃, 93℃/10mm, 205.5℃/atm, d420 0.981, nD20 1.54033, pK25 15.4. |
提纯方法 | It is usually purified by careful fractional distillation under reduced pressure in the absence of air. Benzaldehyde, if present, can be detected by UV absorption at 283nm. It has also been purified by shaking with aqueous KOH and extracting with peroxide-free diethyl ether. After washing with water, the extract is treated with saturated NaHS solution, filtered, washed, dried with CaO and distilled under reduced pressure [Mathews J Am Chem Soc 48 562 1926]. Peroxy compounds can be removed by shaking with a solution of Fe+2 followed by washing the alcohol layer with distilled water and fractionally distilling it. [Beilstein 6 IV 2222.] |
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